Graphical abstract

Exploration of NaSICON Frameworks as Calcium-Ion Battery Electrodes

D. B. Tekliye, A. Kumar, X. Weihang, T. D. Mercy, P. Canepa, and G. S. Gautam; Chem. Mater. 34, 10133 (2022).

BibTeX 
@article{Tekliye2022exploration,
  author  = {Tekliye, D. B. and Kumar, A. and Weihang, X. and Mercy, T. D. and Canepa, P. and Gautam, G. S.},
  title   = {{Exploration of NaSICON Frameworks as Calcium-Ion Battery Electrodes}},
  journal = {Chemistry of Materials},
  volume  = {34},
  pages   = {10133},
  year    = {2022},
  doi     = {10.1021/acs.chemmater.2c02841}
}
PDF
2022-11-11-tekliye-chem-mater-2022.pdf
DOI
10.1021/acs.chemmater.2c02841
GitHub
https://github.com/sai-mat-group/ca-nasicon-electrodes

Abstract

The development of energy storage technologies that are alternative to state-of-the-art lithium-ion batteries but exhibit similar energy densities, lower cost, and better safety is an important step in ensuring a sustainable energy future. Electrochemical systems based on calcium (Ca)-intercalation or deintercalation form such an alternative energy storage technology but require the development of intercalation electrode materials that exhibit reversible Ca-exchange with reasonable energy density and power density performance. To address this issue, we use first-principles calculations to screen over the wide chemical space of sodium superionic conductor (NaSICON) frameworks, with a chemical formula of CaxM2(ZO4)3 (where M = Ti, V, Cr, Mn, Fe, Co, or Ni and Z = Si, P, or S) for Ca electrode materials. We calculate the average Ca2+ intercalation voltage, the thermodynamic stability (at 0 K) of charged and discharged Ca-NaSICON, and the migration barriers of (meta)stable Ca-NaSICON compositions. Importantly, our calculations indicate CaxV2(PO4)3, CaxMn2(SO4)3, and CaxFe2(SO4)3 Ca-NaSICONs to be promising as Ca-cathodes. We find all silicate Ca-NaSICONs to be thermodynamically unstable and hence unsuitable as Ca-cathodes. We report the overall trends in the ground state Ca-vacancy configurations, besides voltages, stabilities, and migration barriers. Our work contributes to unearthing strategies for developing practical calcium-ion batteries, involving polyanionic intercalation frameworks.