Magnesium ion mobility in post-spinels accessible at ambient pressure

Hannah, D. C.; Gautam, G. S.; Canepa, P.; Rong, Z.; Ceder, G.

doi:10.1039/C7CC01092C

Magnesium ion mobility in post-spinels accessible at ambient pressure

D. C. Hannah, G. S. Gautam, P. Canepa, Z. Rong, and G. Ceder; Chem. Commun. 53, 5171–5174 (2017).

BibTeX

@article{Hannah2017magnesium,
  author  = {Hannah, D. C. and Gautam, G. S. and Canepa, P. and Rong, Z. and Ceder, G.},
  title   = {{Magnesium ion mobility in post-spinels accessible at ambient pressure}},
  journal = {Chemical Communications},
  volume  = {53},
  pages   = {5171--5174},
  year    = {2017},
  doi     = {10.1039/C7CC01092C}
}

Abstract

We propose that Ti-containing post-spinels may offer a practically-accessible route to fast multivalent ion diffusion in close-packed oxide lattices, with the caveat that substantial thermodynamic driving forces for conversion reactions exist.